26,874 research outputs found
Note on the derivative of the hyperbolic cotangent
In a letter to Nature (Ford G W and O'Connell R F 1996 Nature 380 113) we
presented a formula for the derivative of the hyperbolic cotangent that differs
from the standard one in the literature by an additional term proportional to
the Dirac delta function. Since our letter was necessarily brief, shortly after
its appearance we prepared a more extensive unpublished note giving a detailed
explanation of our argument. Since this note has been referenced in a recent
article (Estrada R and Fulling S A 2002 J. Phys. A: Math. Gen. 35 3079) we
think it appropriate that it now appear in print. We have made no alteration to
the original note
Use of mathematical derivatives (time-domain differentiation) on chromatographic data to enhance the detection and quantification of an unknown 'rider' peak
Two samples of an anticancer prodrug, AQ4N, were submitted for HPLC assay and showed an unidentified impurity that eluted as a 'rider' on the tail of the main peak. Mathematical derivatization of the chromatograms offered several advantages over conventional skimmed integration. A combination of the second derivative amplitude and simple linear regression gave a novel method for estimating the true peak area of the impurity peak. All the calculation steps were carried out using a widely available spreadsheet program. (C) 2003 Elsevier B.V. All rights reserved
Multi-scale Renormalisation Group Improvement of the Effective Potential
Using the renormalisation group and a conjecture concerning the perturbation
series for the effective potential, the leading logarithms in the effective
potential are exactly summed for scalar and Yukawa theories.Comment: 19 pages, DIAS STP 94-09. Expanded to check large N limit, typo's
corrected, to appear in Phys Rev
Stochastic Spacetime and Brownian Motion of Test Particles
The operational meaning of spacetime fluctuations is discussed. Classical
spacetime geometry can be viewed as encoding the relations between the motions
of test particles in the geometry. By analogy, quantum fluctuations of
spacetime geometry can be interpreted in terms of the fluctuations of these
motions. Thus one can give meaning to spacetime fluctuations in terms of
observables which describe the Brownian motion of test particles. We will first
discuss some electromagnetic analogies, where quantum fluctuations of the
electromagnetic field induce Brownian motion of test particles. We next discuss
several explicit examples of Brownian motion caused by a fluctuating
gravitational field. These examples include lightcone fluctuations, variations
in the flight times of photons through the fluctuating geometry, and
fluctuations in the expansion parameter given by a Langevin version of the
Raychaudhuri equation. The fluctuations in this parameter lead to variations in
the luminosity of sources. Other phenomena which can be linked to spacetime
fluctuations are spectral line broadening and angular blurring of distant
sources.Comment: 15 pages, 3 figures. Talk given at the 9th Peyresq workshop, June
200
Averaged Energy Conditions in 4D Evaporating Black Hole Backgrounds
Using Visser's semi-analytical model for the stress-energy tensor
corresponding to the conformally coupled massless scalar field in the Unruh
vacuum, we examine, by explicitly evaluating the relevant integrals over
half-complete geodesics, the averaged weak (AWEC) and averaged null (ANEC)
energy conditions along with Ford-Roman quantum inequality-type restrictions on
negative energy in the context of four dimensional evaporating black hole
backgrounds. We find that in all cases where the averaged energy conditions
fail, there exist quantum inequality bounds on the magnitude and duration of
negative energy densities.Comment: Revtex, 13 pages, to appear in Phy. Rev.
Measured quantum probability distribution functions for Brownian motion
The quantum analog of the joint probability distributions describing a
classical stochastic process is introduced. A prescription is given for
constructing the quantum distribution associated with a sequence of
measurements. For the case of quantum Brownian motion this prescription is
illustrated with a number of explicit examples. In particular it is shown how
the prescription can be extended in the form of a general formula for the
Wigner function of a Brownian particle entangled with a heat bath.Comment: Phys. Rev. A, in pres
Restrictions on Negative Energy Density in Flat Spacetime
In a previous paper, a bound on the negative energy density seen by an
arbitrary inertial observer was derived for the free massless, quantized scalar
field in four-dimensional Minkowski spacetime. This constraint has the form of
an uncertainty principle-type limitation on the magnitude and duration of the
negative energy density. That result was obtained after a somewhat complicated
analysis. The goal of the current paper is to present a much simpler method for
obtaining such constraints. Similar ``quantum inequality'' bounds on negative
energy density are derived for the electromagnetic field, and for the massive
scalar field in both two and four-dimensional Minkowski spacetime.Comment: 17 pages, including two figures, uses epsf, minor revisions in the
Introduction, conclusions unchange
Casimir Force between a Dielectric Sphere and a Wall: A Model for Amplification of Vacuum Fluctuations
The interaction between a polarizable particle and a reflecting wall is
examined. A macroscopic approach is adopted in which the averaged force is
computed from the Maxwell stress tensor. The particular case of a perfectly
reflecting wall and a sphere with a dielectric function given by the Drude
model is examined in detail. It is found that the force can be expressed as the
sum of a monotonically decaying function of position and of an oscillatory
piece. At large separations, the oscillatory piece is the dominant
contribution, and is much larger than the Casimir-Polder interaction that
arises in the limit that the sphere is a perfect conductor. It is argued that
this enhancement of the force can be interpreted in terms of the frequency
spectrum of vacuum fluctuations. In the limit of a perfectly conducting sphere,
there are cancellations between different parts of the spectrum which no longer
occur as completely in the case of a sphere with frequency dependent
polarizability. Estimates of the magnitude of the oscillatory component of the
force suggest that it may be large enough to be observable.Comment: 18pp, LaTex, 7 figures, uses epsf. Several minor errors corrected,
additional comments added in the final two sections, and references update
Ab initio Molecular Dynamical Investigation of the Finite Temperature Behavior of the Tetrahedral Au and Au Clusters
Density functional molecular dynamics simulations have been carried out to
understand the finite temperature behavior of Au and Au clusters.
Au has been reported to be a unique molecule having tetrahedral
geometry, a large HOMO-LUMO energy gap and an atomic packing similar to that of
the bulk gold (J. Li et al., Science, {\bf 299} 864, 2003). Our results show
that the geometry of Au is exactly identical to that of Au with
one missing corner atom (called as vacancy). Surprisingly, our calculated heat
capacities for this nearly identical pair of gold cluster exhibit dramatic
differences. Au undergoes a clear and distinct solid like to liquid like
transition with a sharp peak in the heat capacity curve around 770 K. On the
other hand, Au has a broad and flat heat capacity curve with continuous
melting transition. This continuous melting transition turns out to be a
consequence of a process involving series of atomic rearrangements along the
surface to fill in the missing corner atom. This results in a restricted
diffusive motion of atoms along the surface of Au between 650 K to 900 K
during which the shape of the ground state geometry is retained. In contrast,
the tetrahedral structure of Au is destroyed around 800 K, and the
cluster is clearly in a liquid like state above 1000 K. Thus, this work clearly
demonstrates that (i) the gold clusters exhibit size sensitive variations in
the heat capacity curves and (ii) the broad and continuous melting transition
in a cluster, a feature which has so far been attributed to the disorder or
absence of symmetry in the system, can also be a consequence of a defect
(absence of a cap atom) in the structure.Comment: 7 figure
Anomalous diffusion in quantum Brownian motion with colored noise
Anomalous diffusion is discussed in the context of quantum Brownian motion
with colored noise. It is shown that earlier results follow simply and directly
from the fluctuation-dissipation theorem. The limits on the long-time
dependence of anomalous diffusion are shown to be a consequence of the second
law of thermodynamics. The special case of an electron interacting with the
radiation field is discussed in detail. We apply our results to wave-packet
spreading
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